How Does the Boiling Point of a Solvent Affect Cleaning Results?

Many younger engineers today have never seen a vapor degreaser and are unfamiliar with the operations or the benefits of the technology. Because of its simplicity, vapor degreasing has proven to be the most consistent and “head-ache” free cleaning process. The “secret sauce” of vapor degreasing  is the low-boiling solvent which makes the magic happen.

Let Thermodynamics Do the Cleaning

Most people are familiar with water cleaning. Water may be the elixir of life, but it’s not a great cleaning solvent because of the inherent limitations of the molecule. To overcome some of these natural limitations, aqueous cleaning processes tweak the systems in three dimensions: they extend the cleaning cycles, or  extend the machines themselves with  more pumps and sprays and air knives, or they add various soaps or saponifiers, All of this adds costs.

The boiling solvent in the degreaser gently cleans the parts without ultrasonics

The boiling solvent in the degreaser gently cleans the parts without ultrasonics

In contrast, vapor degreasing uses simple thermodynamics to clean, starting with these low-boiling solvents. “Low boiling” is a relative term, in comparison to water. These solvents boil from 15˚-70˚C (65°-170°F) depending upon the particular solvent. Many popular solvents boil almost at room temperature, and you can actually point your hand into the boiling liquid without harm.

To begin, a low-boiling solvent is placed in the “boil sump” where the solvent is heated.  Once boiling, the solvent produces a clear, dense vapor that is heavier than air, which rises through the machine gradually displacing the air in the degreaser. This is the “vapor blanket” and helps contain the liquid solvent inside the machine.

Eventually the vapors rise to the first set of refrigeration coils called the “primary condensing coils” (see photo, right). These coils chill the vapors and condense the solvent back into its liquid state. This condensed liquid drips into a trough that wraps around the internal circumference of the machine and is collected in the water separator (since some air-borne humidity from above the vapor blanket also condenses on these same coils) and eventually routed into the “rinse sump.” Since the rinse sump already is filled with clean solvent, the addition of more solvent causes the rinse sump to overflow, spilling the solvent into the same boil sump where it originally came from. This purging maintains a constantly clean rinse sump. It also concentrates any contamination into the boil sump, for easy removal and maintenance.

Benefits of Low-Temperature Cleaning

Because the solvent boils so easily, a number of important benefits become possible:

  • The cleaning system uses very little electricity, which saves money and helps prevent global warming
  • The system avoids dumping large quantities of humidity into the work environment, which water cleaning systems do continually
  • The vapors enhance the cleaning results, easily getting into tight spaces and tiny stand-offs
  • The roiling, bubbling action of the boiling solvent “scrubs” the parts being cleaned very thoroughly but very gently, without ultrasonics
  • The low temperatures enhance worker safety
  • The cleaning systems are substantially smaller than aqueous cleaning systems, without the complex recycling/reverse osmosis filtration systems, which also save money

Here’s a general list of the boiling points of popular cleaning choices, sorted from lowest boiling temperature to highest:

Solvent or Ingredient Boiling Point, ˚C
HFO-1233zd (“Solstice”) 15
HCFC-141b (“Genesolv”)† 32
HFC-365 (“Solvay”) 40
Methylene chloride 40
MicroCare HSFR 41
Methoxytridecafluoroheptene (“Sion”) 47
CFC-113 (“Freon”)† 48
Trans 1,2-Dichloroethylene* 48
HFC-43-10 (“Vertrel”) 55
 Tergo™ process 55
HFE-7100 (“Novec”) 60
Normal Propyl Bromide (nPB) (Bromothane™) 71
1,1,1 Trichloroethane (TCA)† 74
Carbon tetrachloride 77
Trichloroethylene (TCE) >87
Perchloroethylene (Perc) 121

 

Here’s the same data in a chart…

Boiling point of various organic solvents compared

One final note: the boiling point does not affect the cleaning power of the solvent; that is a function of the Kb value and the viscosity, surface tension, densities, and low latent heat of the specific solvent. However, a higher-boiling solvent may be a useful tool when trying to remove insoluble contamination such as wax or buffing compounds because the solvent can melt the contamination and carry it away.

In short, an appropriate boiling point is the enabling trait that makes vapor degreasing so very useful. When the solvents are used in a properly configured cleaning machine, the results are consistent, affordable, fast, reliable, safe and environmentally acceptable.

* Indicates a flammable solvent; this usually is an ingredient in an azeotropic blend.

† Indicates a Class 1 or Class 2 ozone-depleting solvent; no longer used by environmentally responsible companies and countries; included here merely for completeness.